Color cosmetic compositions containing organic oil and silicone mixture

ABSTRACT

A pigmented cosmetic composition comprising at least one silicone compatible organic oil and at least two silicones selected from the group consisting of:  
     (A) D a    
     (B) MD b D′ c D″ d M  
     (C) M e T f    
     (D) M g Q h    
     wherein a is 3-6  
     b is 1-1,000,000, preferably 1-50,000, more preferably 1-5,000  
     c is 0-1,000,000, preferably 0-50,000, more preferably 0-5,000  
     d is 0-1,000,000, preferably 0-50,000, more preferably 0-5,000  
     e is 1-1,000  
     f is 1-1,000  
     g is 1-1,000; and  
     h is 1-1,000.

TECHNICAL FIELD

[0001] The invention is in the field of color cosmetic compositions forapplication to skin and lips.

BACKGROUND OF THE INVENTION

[0002] Recently transfer resistant cosmetic compositions have becomevery popular. Women of the nineties lead busy lives and are interestedin color cosmetic products that are long lasting and comfortable towear. While the current transfer resistant cosmetics stay on the skinvery well, in some cases they tend to be drying and uncomfortable towear. In addition, transfer resistant films also tend to have a mattetexture, which some women do not find attractive. The ideal colorcosmetic composition should be durable and long lasting, comfortable towear, and provide a finish which is semi-matte or even shiny.

[0003] The object of the invention is to provide a color cosmeticcomposition that provides a long lasting durable finish on the skin andis comfortable to wear.

[0004] Another object of the invention is to provide a color cosmeticcomposition that is transfer resistant and provides a semi-matte orshiny finish.

[0005] Another object of the invention is to provide a transferresistant lipstick composition that provides a semi-matte or shinyfinish on the lips.

SUMMARY OF THE INVENTION

[0006] The invention comprises a pigmented cosmetic compositioncomprising at least one silicone compatible organic oil and at least twosilicones selected from the group consisting of:

[0007] (A) D_(a)

[0008] (B) MD_(b)D′_(c)D″_(d)M

[0009] (C) M_(c)T_(f)

[0010] (D) M_(g)Q_(h)

[0011] wherein a is 3-6

[0012] b is 1-1,000,000, preferably 1-50,000, more preferably 1-5,000

[0013] c is 0-1,000,000, preferably 0-50,000, more preferably 0-5,000

[0014] d is 0-1,000,000, preferably 0-50,000, more preferably 0-5,000

[0015] e is 1-1,000

[0016] f is 1-1,000

[0017] g is 1-1,000; and

[0018] h is 1-1,000.

DETAILED DESCRIPTION

[0019] The color cosmetic composition of the invention may be a lipstickin the stick or liquid form, blush, eyeshadow, foundation, concealer,and the like, and may be in the anhydrous or emulsion form. Thecomposition contains at least one silicone compatible organic oil and atleast two silicones, preferably three, silicones selected from the groupconsisting of (A)-(D), above.

[0020] I. Silicone Compatible Organic Oil

[0021] The silicone compatible organic oil may be an ester, hydrocarbonoil, or an animal, vegetable, or mineral oil. The term “compatible”means that the organic oil is soluble or dispersible in the siliconemixture to form a stable solution or dispersion. The organic oil is aliquid at room temperature (25° C.) and preferably has a viscosity ofabout 10 to 600,000, preferably 20 to 500,000, more preferably 50 to300,000 centipoise at 25° C. The composition comprises 0.1-80%,preferably 0.5-70%, more preferably 1-50% by weight of the totalcomposition of the silicone compatible organic oil.

[0022] A. Esters

[0023] Suitable silicone compatible organic esters are mono-, di-, andtriesters. The composition may comprise one or more esters selected fromthe group, or mixtures thereof. Preferably the composition contains amixture of di- and triesters, and in a ratio of 0.1-10% diester and0.1-15% triester, by weight of the total composition. Particularlypreferred compositions comprise a mixture of mono-, di- and triesters ina ratio of 0.01-10% monoester, 0.1-10% diester, and 0.1-15% triester,all percentages being by weight of the total composition.

[0024] 1. Monoesters

[0025] Monoesters are defined as esters formed by the reaction of amonocarboxylic acid having the formula R—COOH, wherein R is a straightor branched chain saturated or unsaturated alkyl having 2 to 30 carbonatoms, or phenyl; and an alcohol having the formula R—OH wherein R is astraight or branched chain saturated or unsaturated alkyl having 2-30carbon atoms, or phenyl. Both the alcohol and the acid may be substituedwith one or more hydroxyl groups, and in one preferred embodiment of theinvention the acid is an alpha hydroxy acid. Either one or both of theacid or alcohol may be a “fatty” acid or alcohol, ie. may have fromabout 6 to 22 carbon atoms. Examples of monoester oils that may be usedin the compositions of the invention include hexyldecyl benzoate, hexyllaurate, hexadecyl isostearate, hexydecyl laurate, hexyldecyl octanoate,hexyldecyl oleate, hexyldecyl palmitate, hexyldecyl stearate,hexyldodecyl salicylate, hexyl isostearate, butyl acetate, butylisostearate, butyl oleate, butyl octyl oleate, cetyl palmitate, ceyloctanoate, cetyl laurate, cetyl lactate, cetyl isononanoate, cetylstearate, stearyl lactate, stearyl octanoate, stearyl heptanoate,stearyl stearate, and so on. It is understood that in the abovenomenclature, the first term indicates the alcohol and the second termindicates the acid in the reaction, i.e. stearyl octanoate is thereaction product of stearyl alcohol and octanoic acid. Preferred ismonoester which is the reaction product of an aliphatic C₂₋₈ alcohol anda C₁₄₋₂₂ fatty acid, more particularly, the reaction product of a hexylalcohol and lauric acid, also referred to as hexyl laurate.

[0026] 2. Diesters

[0027] Suitable diesters that may be used in the compositions of theinvention are the reaction product of a dicarboxylic acid and analiphatic or aromatic alcohol. The dicarboxylic acid may contain from 2to 30 carbon atoms, and may be in the straight or branched chain,saturated or unsaturated form. The dicarboxylic acid may be subsitutedwith one or more hydroxyl group. The aliphatic or aromatic alcohol mayalso contain 2 to 30 carbon atoms, and may be in the straight orbranched chain, saturated, or- unsaturated form. The aliphatic oraromatic alcohol may be substituted with one or more substitutents suchas hydroxyl. Preferably, one or more of the acid or alcohol is a fattyacid or alcohol, i.e. contains 14-22 carbon atoms. The dicarboxylic acidmay also be an alpha hydroxy acid. Examples of diester oils that may beused in the compositions of the invention include diisostearyl malate(the reaction product of isostearic alcohol and malic acid), neopentylglycol dioctanoate (the reaction product of neopentyl glycol and 2-ethylhexanoic acid), dibutyl sebacate (reaction product of butyl alcohol andsebacic acid), di-C₁₂₋₁₃ alkyl malate (reaction product of C12-13alcohol and malic acid), dicetearyl dimer dilinoleate (reaction productof cetearyl alcohol and adipic acid), dicetyl adipate (reaction productof cetyl acohol and adipic acid), diisocetyl adipate (reaction productof hexadecyl alcohol and adipic acid), diisononyl adipate (reactionproduct of isononyl alcohol and adipic acid), diisostearyl dimerdilinoleate (reaction product of isostearyl alcohol and dilinoleicacid), disostearyl fumarate (reaction product of isostearyl alcohol andfumaric acid), and so on.

[0028] 3. Triesters

[0029] Suitable triesters comprise the reaction product of atricarboxylic acid and an aliphatic or aromatic alcohol. As with themono- and diesters mentioned above, the acid and alcohol contain 2 to 30carbon atoms, and may be saturated or unsatured, straight or branchedchain, and may be substituted with one or more hydroxyl groups.Preferably, one or more of the acid or alcohol is a fatty acid oralcohol containing 14 to 22 carbon atoms. Examples of triesters includetriarachidin (reaction product of glycerin and arachidic acid), tributylcitrate (reaction product of butyl alcohol and citric acid), tri C12-13alkyl citrate (reaction product of C12-13 alcohol and citric acid),tricaprylin (reaction product of glycerin and caprylic acid),tricaprylyl citrate (reaction product of capryl alcohol and citricacid), tridecyl behenate (reaction product of tridecyl alcohol andbehenic acid), trioctyldodecyl citrate (reaction product of octyldodecylalcohol and citric acid), tridecyl behenate (reaction product oftridecyl alcohol and behenic acid), tridecyl cocoate (reaction productof tridecyl alcohol and coconut acid), tridecyl isononanoate (reactionproduct of tridecyl alcohol and isononanoate), and so on. Preferred is atriester which is the reaction product of an alpha hydroxy acid and aguerbet alcohol having 6 to 30 carbon atoms, in particular the reactionproduct of citric acid and octyldodecyl alcohol, referred to astrioctyldodecyl citrate.

[0030] B. Hydrocarbon Oils

[0031] Suitable hydrocarbon oils used in the compositions of theinvention may be volatile or nonvolatile. The term “volatile” means thatthe oil has a measureable vapor pressure, or a vapor pressure of atleast 2 mm. of mercury at 20° C. The term “nonvolatile” means that theoil has a vapor pressure of less than 2 mm. of mercury at 20° C.

[0032] 1. Volatile Hydrocarbon Oils

[0033] Examples of volatile hydrocarbon oils that may be used in thecompositions of the invention include various straight or branched chainparaffinic hydrocarbons having 5 to 20 carbon atoms, more preferably8-20 carbon atoms. Suitable hydrocarbons include pentane, hexane,heptane, decane, dodecane, tetradecane, tridecane, and C₈₋₂₀isoparaffins as disclosed in U.S. Pat. Nos. 3,439,088 and 3,818,105,both of which are hereby incorporated by reference. Preferred volatileparaffinic hydrocarbons have a molecular weight of 70-225, preferably160 to 190 and a boiling point range of 30 to 320, preferably 60-260degrees C., and a viscosity of less than 10 cs. at 25 degrees C. Suchparaffinic hydrocarbons are available from EXXON under the ISOPARStrademark, and from the Permethyl Corporation. Suitable C₁₂ isoparaffinsare manufactured by Permethyl Corporation under the tradename Permethyl99A. Another C₁₂ isoparaffin (isododecane) is distributed by Presperseunder the tradename Permethyl 99A. Various C₁₆ isoparaffins commerciallyavailable, such as isohexadecane (having the tradename Permethyl R), arealso suitable.

[0034] 2. Nonvolatile Hydrocarbon Oils

[0035] Suitable nonvolatile hydrocarbon oils include isoparaffins andolefins having greater than 20 carbon atoms. Examples of suchhydrocarbon oils include C₂₄₋₂₈ olefins, C₃₀₋₄₅ olefins, C₂₀₋₄₀isoparaffins, hydrogenated polyisobutene, mineral oil,pentahydrosqualene, squalene, squalane, and mixtures thereof.

[0036] C. Lanolin Oil

[0037] Also suitable for use in the composition is lanolin oil orderivatives thereof such as hydroxylated lanolin, isobutylated lanolinoil, acetylated lanolin, acetylated lanolin alcohol, and so on.

[0038] Preferred compositions of the invention comprise a siliconecompatible organic oil selected-from-the group consisting of:

[0039] (i) monoesters,

[0040] (ii) diesters,

[0041] (iii) triesters

[0042] (iv) volatile hydrocarbons

[0043] (v) lanolin; and

[0044] (vi) mixtures thereof.

[0045] II. Silicone Mixture

[0046] The composition of the invention comprises at least two siliconesselected from the group consisting of:

[0047] (A) D_(a)

[0048] (B) MD_(b)D′_(c)D″_(d)M

[0049] (C) M_(e)T_(f)

[0050] (D) M_(g)Q_(h)

[0051] wherein a is 3-6

[0052] b is 1-1,000,000, preferably 1-50,000, more preferably 1-5,000

[0053] c is 0-1,000,000, preferably 1-50,000, more preferably 1-5,000

[0054] d is 0-1,000,000, preferably 1-50,000, more preferably 1-5,000

[0055] e is 1-1,000

[0056] f is 1-1,000

[0057] g is 1-1,000; and

[0058] h is 1-1,0000.

[0059] The term “M” means a monofunctional monomer unit, “D” means adifunctional monomer unit, “T” means a trifunctional monomer unit, and“Q” a quadrifunctional monomer unit. Primes, e.g. D′, are used toindicate substitutents other than methyl. The silicone mixture comprises1-75%, preferably 10-70%, more preferably 15-60% by weight of the totalcomposition of the total composition.

[0060] A. D_(a) Silicone

[0061] The silicone mixture may comprise one or more silicones havingthe general formula Da, wherein D is a difunctional cyclic monomer, inparticular dimethylsiloxy, and a is 3-6.Preferably, the compositioncomprises 1-40%, more preferably 3-35%, most preferably 5-30% by weightof the total composition of the D_(a) silicone. D_(a) silicones arecyclic silicones wherein a is 4 to 6, having the general formula:

[0062] wherein=3-6.

[0063] Such cyclic volatile silicones are available from variouscommercial sources including Dow Corning Corporation and GeneralElectric. The Dow Corning volatile silicones are sold under thetradenames Dow Corning 244, 245, 344, and 200 fluids. These fluidscomprise octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, andmixtures thereof.

[0064] B. The MD_(b)D′_(c)D″_(d)M Silicone

[0065] The silicone mixture used in the compositions of the inventionmay comprise one or more silicones having the general formulaMD_(b)D′_(c)D″_(d)M, wherein M is a monofunctional monomer, D is adifunctional monomer, and D′ and D″ are difunctional monomers havingsubstituents other than methyl, and wherein b, c, and d are as definedabove. The composition may comprise 0.5-45%, preferably 1-40%, morepreferably 2-35% by weight of the total composition of one or moreMD_(b)D′_(c)D″_(d)M silicones. Preferably this silicone is a mixturecomprising at least one silicone which is a liquid at room temperatureand at least one silicone which is a solid or semi-solid at roomtemperature (e.g. 25° C.)

[0066] In the above formula, M has the empirical formula R₃SiO_(0.5), orR¹RRSiO0_(0.5), or R¹R²RSiO0₅, or R¹R²R³SiO_(0.5), wherein R is methyl,and R¹, R², and R³ are each independently a C₁₋₆ straight or branchedchain alkyl, phenyl, diisostearoyl trimethylol propane, ordilauroyltrimethylolpropane. Preferably M has the empirical formulaR₃SiO_(0.5), wherein R is methyl.

[0067] D has the empirical formula R₂SiO_(1.0) wherein R is methyl.

[0068] D′ has the empirical formula RR⁴SiO_(1.0) or R⁴R⁵SiO_(1.0)wherein R is methyl and R⁴ and R⁵ are each independently a C₇₋₃₀straight or branched chain alkyl, alkenyl, hydroxy-substituted alkyl,fluoro-substituted alkyl, phenyl, trimethylsiloxy, and the like.

[0069] D″ has the empirical formula RR⁶SiO_(1.0) or R⁶R⁷ _(1.0) whereinR is methyl and R⁶ and R⁷ are each independently a hydrophilic radicalsuch as (CH₂)_(o)—O—PE) where PE is (—C₂H₄O)_(x)(—C₃H₆O)_(y)H, ando=0-40; wherein x is 1-10,000 and y is 0-10,000; wherein x is 1-10,000and y is 0-10,000.

[0070] Preferred is where M is R₃SiO_(0.5) wherein R is methyl (e.g.trimethylsiloxy), D is R₂SiO_(1.0) wherein R is methyl (e.g.dimethylsiloxy); and b is 1-50,000; and c and d are 0; wherein thecompound is dimethicone. Preferably the dimethicone is a liquid at roomtemperature and has a viscosity ranging from about 10-100,000 centipoiseat 25° C.

[0071] Also preferred is where M is trimethylsiloxy, D isdimethylsiloxy, b is 1-50,000, as above, and wherein D′ is RR⁴SiO_(1.0)wherein R is methyl and R⁴ is a C₇₋₃₀, preferably C₁₄₋₂₀ straight orbranched chain alkyl; c is 1-50,000; and d is 0; wherein the compound isa C₁₄₋₂₀ alkyl dimethicone, in particular, cetyl dimethicone.Preferably, this silicone is a waxy solid or semi-solid at 25° C.

[0072] Also preferred is where M is trimethylsiloxy, D isdimethylsiloxy, b is 1-50,000, D′ is RR⁴SiO_(1.0) wherein R is methyland R⁴ is a C₇₋₃₀, preferably C₁₄₋₂₀ straight or branched chain alkyl;and c is 1-50,000; and D″ is RR⁶SiO_(1.0) wherein R⁶ is methyl and R⁶ is(CH₂)_(o)—O—PE wherein o is 0-40 and PE is (C₂H₄O)_(x)(C₃H₆O)_(y)H andwherein x is 1-10,000 and y is 0-10,000. A particularly preferredcompound having this general formula is cetyl dimethicone copolyol,tradename ABIL WE 09 or ABIL WS 08. The cetyl dimethicone copolyol maybe used alone or in conjunction with other non-silicone organicemulsifiers and oils. Preferred is where the cetyl dimethicone copolyolis in an admixture with other non-silicone organic emulsifiers and oils.In particular, blends of 25-50% of the organosiloxane emulsifier, 25-50%of a non-silicqne organic emulsifier, and 25-50% by weight monoesteroils are preferred. For example, the mixtures identified by the C.T.F.A.names cetyl dimethicone copolyol (and) polyglyceryl 4-isostearate (and)hexyl laurate, or cetyl dimethicone copolyol (and) polyglyceryl-3 oleate(and) hexyl laurate both work well. These blends contain approximately25-50% of each ingredient, for example ABIL WE 09 containsapproximately, by weight of the total ABIL composition, 25-50% cetyldimethicone copolyol, 25-50%, polyglyceryl 4-isostearate, and 25-50% ofhexyl laurate which is a monoester oil.

[0073] C. M_(e)T_(f)

[0074] The composition of the invention may comprise at least onesilicone having the general formula M_(e)T_(f) wherein M has theempirical formula as defined above with respect to theMD_(b)D′_(c)D″_(d)M silicone and T is a trifunctional siloxy unit havingthe empirical formula RSiO_(1.5) or R⁸SiO_(1.5), wherein R is methyl andR⁸ is a C₂₋₄₀ straight or branched chain alkyl which may be substitutedwith one or more hydroxyl or halogen radicals. Typically, preferredM_(e)T_(f) silicones are made by formed by the hydrolysis andcondensation of methyltrimethoxy silane according to procedures wellknown in the art. Preferably the M_(e)T_(f) silicone is a solid at roomtemperature, and is more preferably in the particulate form havingparticle size of about 0.05 to 50 microns. In the preferred embodimentof the invention the composition comprises 0.1-15%, preferably 0.5-12%,more preferably 1-8% by weight of the total composition of theM_(e)T_(f) silicone. One type of M_(e)T_(f) silicone that may be used inthe invention has the general formula M₃T and is referred to as1,1,1,3,5,5,5-heptamethyl-3-trimethylsiloxy-trisiloxane. Preferred areM_(e)M_(f) silicones wherein M is R₃SiO_(0.5) and T is RSiO_(1.5)wherein R is methyl, and e and f are each 1-1,000, preferably 1-500.Particularly preferred is a M_(e)T_(f) silicone which ispolymethylsilsesquioxane. This silicone may be purchased from KoboProducts Inc., under the tradename Tospearl 145A. The silicone is a finewhite powder having a particle size of 3.5 to 6.0 microns.

[0075] D. M_(g)Q_(h)

[0076] The composition of the invention may comprise at least onesilicone having the general formula M_(g)Q_(h) wherein M, g, and h areas defined above, and Q is a quadrifunctional siloxy unit having theempirical formula SiO₂ or SiO_(4/2). Suitable M_(g)Q_(h) silicones aredisclosed in U.S. Pat. Nos. 4,725,658 and 5,334,737, which are herebyincorporated by reference. These particular silicones are siliconeesters which may be liquid or solid at 25° C., and have the generalformula M₂Q. The preferred M_(g)Q_(h) silicones are made by hydrolysisand condensation of trimethoxysilane and/or trimethylchlorosilaneaccording to procedures well known in the art, thus they will containvery small amounts of silanol and/or alkoxy endgroups. Such silicones,also referred to as MQ resins, and their manufacture, are set forth inU.S. Pat. Nos. 2,676,182; 3,541,205, and 3,836,437, all of which arehereby incorporated by reference in their entirety. The M_(g)Q_(h)silicones used in the compositions of the invention generally satisfythe relationship: RnSiO(4-n)/2 wherein n is a value between 1.0 and 1.50and R is methyl. Preferably, the M_(g)Q_(h) resin is trimethylsiloxysilicate and the ratio of M to Q units is 0.5 to 1 to 1.5 to 1respectively and is in the form of a solid particulate having a particlesize ranging from about 0.05 to 50 microns. Trimethylsiloxy silicate isavailable from Dow Corning Corporation under the tradename Dow Corning749 fluid, which is a fluid containing about 50% trimethylsiloxysilicate and about 50% cyclomethicone. The fluid has a viscosity ofabout 200 to 700 centipoise at 25° C., and a specific gravity of 1.00 to1.10 at 25° C., and a refractive index of 1.40 to 1.41. Preferably, thecompositions of the invention comprise about 1-45%, preferably 2-40%,more preferably 5-30% by weight of the total composition of theM_(g)Q_(h) silicone.

[0077] III. Other Ingredients

[0078] The compositions of the invention may additionally comprise otheringredients which enhance the performance of the composition, such asparticulate matter, synthetic polymers, waxes, sunscreens,preservatives, antioxidants, and so on.

[0079] A. Particulate Matter

[0080] The composition of the invention may contain 1-50%, preferably7-45%, more preferably 10-40%, by weight of the total composition, ofpigments and/or powders, referred to as particulate matter, having aparticle size of 0.02 to 100, preferably 0.5 to 100, microns. Theparticulate matter may be colored or non-colored (for example white).Suitable particulates include bismuth oxychloride, titanated mica, fumedsilica, spherical silica, polymethylmethacrylate, polyethylene,polypropylene, micronized teflon, boron nitride, acrylate copolymers,aluminum silicate, aluminum starch octenylsuccinate, bentonite, calciumsilicate, cellulose, chalk, corn starch, diatomaceous earth, fuller'searth, glyceryl starch, hectorite, hydrated silica, kaolin, magnesiumaluminum silicate, magnesium trisilicate, maltodextrin, montmorillonite,microcrystalline cellulose, rice starch, silica, talc, mica, titaniumdioxide, zinc laurate, zinc myristate, zinc rosinate, alumina,attapulgite, calcium carbonate, calcium silicate, dextran, kaolin,nylon, silica silylate, silk powder, sericite, soy flour, tin oxide,titanium hydroxide, trimagnesium phosphate, walnut shell powder, ormixtures thereof. The above mentioned powders may be surface treatedwith lecithin, amino acids, mineral oil, silicone oil or various otheragents either alone or in combination, which coat the powder surface andrender the particles more lipophilic in nature.

[0081] The particulates may also include various organic and inorganicpigments. The organic pigments are generally various aromatic typesincluding azo, indigoid, triphenylmethane, anthraquinone, and xanthinedyes which are designated as D&C and FD&C blues, browns, greens,oranges, reds, yellows, etc. Organic pigments generally consist ofinsoluble metallic salts of certified color additives, referred to asthe Lakes, in particular the Lakes of D&C and FD&C colors. Inorganicpigments include iron oxides, ultramarines, chromium, chromium hydroxidecolors, and mixtures thereof.

[0082] Preferably the composition will contain both pigmented andnon-pigmented particulates. Obviously the percentage of pigments used inthe particulate phase will depend on the type of cosmetic beingformulated. Color cosmetics generally have a much higher concentrationof color than other types of cosmetics. Generally the weight ratio ofpigmented to non-pigmented particulates range from 1:50 to 50:1. Itshould be noted that particulates that are white or have no color areconsidered non-pigmented particulates in accordance with the invention,while particulates which exhibit color other than white are consideredpigmented particulates in accordance with the invention.

[0083] B. Wax

[0084] Preferably, the composition comprises about 0.1-70%, preferably1-30%, more preferably 1-25% by weight of a cosmetically acceptablenatural or synthetic wax. The waxes that can be used are solid orsemi-solid waxes having a melting point of 30 to 120° C. and generallyincludes animal waxes, plant waxes, mineral waxes, silicone waxes,synthetic waxes, and petroleum waxes.

[0085] Examples of waxes in accordance with the invention includebayberry, beeswax, candelilla, carnauba, ceresin, cetyl esters,hydrogenated jojoba oil, hydrogenated jojoba wax, hydrogenatedmicrocrystalline wax, hydrogenated rice bran wax, japan wax, jojobabutter, jojoba esters, jojoba wax, lanolin wax, microcrystalline wax,mink wax, montan acid wax, montan wax, ouricury wax, ozokerite,paraffin. PEG-6 beeswax, PEG-8 beeswax, rice bran wax, shellac wax,spent grain wax, sulfurized jojoba oil, synthetic beeswax, syntheticcandelilla wax, synthetic camauba wax, synthetic japan wax, syntheticjojoba oil, synthetic wax, stearoxy dimethicone, dimethicone behenate,stearyl dimethicone, and the like, as well-synthetic homo- and copolymerwaxes from the ethylene series. In the preferred embodiment of theinvention the waxes are either either alone or in combination with apetroleum wax such as shellac, and a plant wax such as ozokerite.

[0086] C. Synthetic Polymers

[0087] The compositions of the invention preferably comprise one or moresynthetic polymers. Suggested ranges are 0.1-30%, preferably 0.5-25%,more preferably 1-20% by weighi of the total composition. The syntheticpolymer will cause the composition to give an improved film on the skinor lips, and may also cause improved transfer resistance and/orplasticity of the film and improved adhesion of the film to skin andlips. The synthetic polymer may be a liquid or solid at 25° C., but ispreferably a liquid. A variety of synthetic polymers are suitable,including homo- or copolymers of monomers such as acrylic acid,methacrylic acid or C₁₋₃₀ esters of acrylic or methacrylic acid, vinylpyrrolidone, saturated methylene diphenyl diisocyanate, C₁₋₃₀ hydroxyesters of acrylic or methacrylic acid, vinyl acetate, vinylisodecanoate, styrene, and olefins such as ethylene, propylene, butene.pentene, decene, hexadecene, and so on. The synthetic polymers may becopolymers of the monomer units mentioned above, or may be copolymerizedwith various organic compounds such as polyalkylene glycols, paraffinichydrocarbons, alkoxylated alcohols and the like. Preferred arecopolymers of monomers such as vinyl pyrrolidone, saturated methylenediphenyl diisocyanate, acrylic acid or methacrylic acid and C₁₋₃₀ estersthereof, or olefins; and organic compounds such as alkoxylated alcohols,or polyalkylene glycols. Examples of suitable alkoxylated alcoholsinclude beheneth, steareth, ceteth, laureth, and so on, where the numberof repeating ethylene oxide units ranges from 2 to 200. Examples ofsuitable alkylene glycols include ethylene glycol, propylene glycol,butylene glycol and so on. One preferred synthetic polymer is thecopolymer of vinylpyrrolidone and an olefin, hexadecene, known asPVP/hexadecene copolymer, which is sold by International SpecialtyProducts under the tradename Ganex. Another preferred synthetic polymeris a copolymer of saturated methylene diphenyl diisocyanate and apolyalkylene glycol, in particular, polypropylenel glycol, which isknown as PPG-51 SMDI copolymer. This copolymer is available fromPenederm under the tradename Polyolprepolymer-14.

[0088] D. Sunscreens

[0089] Preferably, the composition contains one or more sunscreens in arange of about 0.01-10%, preferably 0.05-8%, more preferably 0.1-5% byweight of the total composition. A sunscreen is defined as an ingredientthat absorbs at least 85 percent of the light in the UV range atwavelengths from 290 to 320 nanometers, but transmit UV light atwavelengths longer than 320 nanometers. Sunscreens generally work in oneof two ways. Particulate materials, such as zinc oxide or titaniumdioxide, as mentioned above, physically block ultraviolet radiation.Chemical sunscreens, on the other hand, operate by chemically reactingupon exposure to UV radiation. Suitable sunscreens that may be includedin the compositions of the invention are set forth on page 582 of theCTFA Cosmetic Ingredient Handbook, Second Edition, 1992, as well as U.S.Pat. No. 5,620,965, both of which are hereby incorpated by reference.Examples of such sunscreen materials are p-aminobenzoic acid (PABA),cinoxate, diethanolamine p-methoxycinnamate (DEA-methoxycinnamate),Digalloyl trioleate, dioxybenzone (Benzophenone-8), ethyl4-[bis-(hydroxypropyl)] amnobenzoate (ethyl dihydroxypropyl PABA),2-ethylhexyl-2-cyano-3,3 -diphenylacrylate (octocrylene), ethylhexylp-methoxycinnamate (Octyl methoxycinnamate), 2-ethylhexyl salicylate(Octyl salicylate), glyceryl aminobenzoate (Glyceryl PABA), homosalate,lawsone with dihydroxyacetone, menthyl anthranilate, oxybenzone(Benzophenone-3), Padimate A (Pentyl Dimethyl PABA), Padimate O, (OctylDimethyl PABA), 2-Phenylbenzimidazole-5-sulfonic acid(Phenylbenzimidazole Sulfonic acid), Red Petrolatum, Sulisobenzone(Benzophenone-4), triethanolamine salicylate (TEA-Salicylates), and soon.

[0090] E. Preservatives

[0091] Preferably the composition comprises one or more preservatives inranges of about 0.001-10%, preferably 0.005-8%, more preferably 0.01-5%by weight of the total composition. Examples of suitable preservativesare parabens, such as methyl, ethyl, and propyl parabens, and the like.

[0092] F. Antioxidants and/or Vitamins

[0093] The compositions of the invention may contain vitamins and/orcoenzymes, as well as antioxidants. If so, 0.001-10%, preferably0.01-8%, more preferably 0.05-5% by weight of the total composition aresuggested. Suitable vitamins include ascorbic acid and derivativesthereof, the B vitamins such as thiamine, riboflavin, pyridoxin, and soon, as well as coenzymes such as thiamine pyrophoshate, flavin adenindinucleotide, folic acid, pyridoxal phosphate, tetrahydrofolic acid, andso on. Also Vitamin A and derivatives thereof are suitable. Examples areVitamin A palmitate, acetate, or other esters thereof, as well asVitamin A in the form of beta carotene. Also suitable is Vitamin E andderivatives thereof such as Vitamin E acetate, nicotinate, or otheresters thereof. In addition, Vitamins D and K are suitable.

[0094] Suitable antioxidants are ingredients which assist in preventingor retarding spoilage. Examples of antioxidants suitable for use in thecompositions of the invention are potassium sulfite, sodium bisulfite,sodium erythrobate, sodium metabisulfite, sodium sulfite, propylgallate, cysteine hydrochloride, butylated hydroxytoluene, butylatedhydroxyanisole, and so on.

[0095] G. Biological Additives

[0096] The composition may comprise one or more biological additives.Suggest ranges are about 0.001-8%, preferably 0.01-6%, more preferably0.05-5% by weight of the total composition. Suitable biologicaladditives include extracts of plant or animal matter, preferably plantmatter. Examples of desireable biological additives include extracts ofaloe, camilla, acacia, blackberry, blueberry, carrot, and so on.

[0097] The compositions may also contain a variety of other ingredientssuch as humectants, water, emollients, and so on.

[0098] The invention will be further described in connection with thefollowing examples, which are set forth for the purposes of illustrationonly.

EXAMPLE 1

[0099] A liquid lipstick was made according to the following formula:w/w % 1 Shellac wax 1.000 (wax) 1 Synthetic wax 0.750 (wax) 1PVP/hexadecene copolymer 2.000 (synthetic polymer) 1 Neopentyl glycoldioctanoate 5.600 (diester) 1 Trioctyldodecyl citrate 3.000 (triester) 1Cetyl dimethicone 10.000 (MD_(b)D’_(c)D”_(d)M - liquid) 1 Stearldimethicone 1.500 (MD_(b)D’_(c)D”_(d)M - waxy solid) 1 PPG-51/SMDICopolymer 7.000 (synthetic polymer) 1 Octyl methoxycinnamate 2.200(sunscreen) 1 Methyl paraben 0.300 (preservative) 1 Propyl paraben 0.100(preservative) 1 Butylated hydroxy anisole 0.200 (antioxidant) 1 Sorbicacid 0.200 (antioxidant) 5 Cyclomethicone/trimethylsiloxy 34.68 (D_(a)liquid + M_(g)Q_(h) solid) silicate (50:50) 1 Cetyl dimethiconecopolyol/ 3.350 (MD_(b)D’_(c)D”_(d)M liquid +polyglyceryl-4-isostearate/hexyl nonionic surfactant + laurate(33:34:33) monoester) surfactant + monoester) 3 D&C Red #7 Calcium Lake0.180 (pigment) 3 FD&C Yellow #5 Aluminum 0.120 (pigment) Lake 3 Rediron oxide 0.420 (pigment) 3 Black iron oxide 0.180 (pigment) 2Dimethicone 4.800 (MD_(b)D’_(c)D”_(d)M - liquid) 2 Acrylates copolymer1.200 (powder) 4 Titanium dioxide, mica, iron 3.500 (pigment + powder)oxides 4 Bismuth oxychloride 3.500 (powder) 4 Polymethylsilsesquioxane3.000 (M_(e)T_(f)) 4 Mica 11.320 (powder)

[0100] Separately, the Sequence 2 ingredients were roller milledtogether. Separately, the Sequence 3 ingredients were roller milled in aportion of the Sequence 5 ingredients. The Sequence 1 ingredients werecombined and heated to 95° C. with mixing until the ingredients weremixed. The Sequence 2 and Sequence 3 premixes were added to the Sequence1 mixture. The batch was covered for the remainder of the procedure. Thetemperature of the mixture was reduced to 85° C. The Sequence 4ingredients were then added, followed by the Sequence 5 ingredients. Thetemperature was further reduced to 80° C. The composition was pouredinto vials and allowed to cool to room temperature.

EXAMPLE 2

[0101] A lipstick in the stick form was made according to the followingformula: w/w % 1 Synthetic wax 4.00 (wax) 1 Ozokerite 0.80 (wax) 1Shellac wax 1.50 (wax) 1 Diisostearyl malate 8.00 (diester) 1 Cetyldimethicone 12.00 (MD_(b)D’_(c)D”_(d)M) 1 PPG-51/SMDI copolymer 6.00(synthetic polymer) 1 Octyl methoxycinnamate 2.20 (sunscreen) 1 Propylparaben 0.10 (preservative) 1 Butylated hydroxy anisole 0.10(antioxidant) 1 Stearyl dimethicone 1.55 (MD_(b)D’_(c)D”_(d)M) 1 VitaminE acetate 2.00 (vitamin) 1 Aloe extract 1.00 (biological additive) 2Pigments 10.45 (pigment) 3 Titanium dioxide/mica 5.00 (powder) 3Bismuthoxychloride 2.00 (powder) 3 Polymethylsilsesquioxane 4.00(M_(e)T_(f)) 3 Mica 5.10 (powder) 5 Lanolin oil 1.00 (oil) 5 Dimethicone3.00 (MD_(b)D’_(c)D”_(d)M) 6 Cyclomethicone/ 25.20(MD_(b)D’_(c)D”_(d)M + M_(g)Q_(h)) trimethylsiloxysilicate (50:50) 4Isododecane 5.00 (hydrocarbon)

[0102] The Sequence 2 ingredients were roller milled into a portion ofthe Sequence 6 ingredients. The mixture was combined with the Sequence 1ingredients and heated with mixing to a temperature of 95° C. untiluniform. The remaining Sequence 2 ingredients were added to the mixture.The batch was covered for the remainder of the procedure. The heat wasreduced to 85° C. The Sequence 3 and Sequence 4 ingredients were addedand mixed well. The Sequence 5 ingredients were combined and added tothe mixture, followed by the Sequence 6 ingredients. The mixture waspoured into lipstick molds when the temperature reached 85° C. andallowed to cool to form sticks.

We claim:
 1. A pigmented cosmetic composition comprising at least onesilicone compatible organic oil and at least two silicones selected fromthe group consisting of: (A) D_(a) (B) MD_(b)D′_(c)D″_(d)M (C)M_(e)T_(f) (D) M_(g)Q_(h) wherein a is 3-6 b is 1-1,000,000, preferably1-50,000, more preferably 1-5,000 c is 0-1,000,000, preferably 0-50,000,more preferably 0-5,000 d is 0-1,000,000, preferably 0-50,000, morepreferably 0-5,000 e is 1-1,000 f is 1-1,000 g is 1-1,000; and h is1-1,000.
 2. The composition of claim 1 wherein the silicone compatibleorganic oil is selected from the group consisting of: (a) a mono-, di-,or triester, (b) a hydrocarbon oil, (c) lanolin oil; and (d) mixturesthereof.
 3. The composition of claim 2 wherein the monoester is thereaction product of a C₆₋₂₂ fatty acid and a C₂₋₃₀ aliphatic alcohol. 4.The composition of claim 3 wherein the monoester is the reaction productof a C₂₋₈ alcohol and a C₁₄₋₂₂ fatty acid.
 5. The composition of claim 4wherein the monoester is the reaction product of hexyl alcohol andlauric acid.
 6. The composition of claim 2 wherein the diester is formedby the reaction of a fatty alcohol and a dicarboxylic acid.
 7. Thecomposition of claim 6 wherein the fatty alcohol has 14 to 22 carbonatoms, and the dicarboxylic acid is an alpha hydroxy acid.
 8. Thecomposition of claim 7 wherein the fatty alcohol is isostearyl alcoholand the alpha hydroxy acid is malic acid.
 9. The composition of claim 2wherein the triester is the reaction product of a tricarboxylic acid andan aliphatic or aromatic alcohol.
 10. The composition of claim 9 whereinthe tricarboxylic acid is an alpha hydroxy acid and the aliphaticalcohol has 14 to 22 carbon atoms.
 11. The composition of claim 1wherein the Da silicone is a cyclic silicone having the formula:

wherein=3-6.
 12. The composition of claim 1 wherein theMD_(b)D_(c)′D_(d)″M silicone M is trimethylsiloxy; D is dimethylsiloxy;b is 1-50,000; and c and d are 0; the compound being dimethicone. 13.The composition of claim 12 wherein the dimethicone is liquid and has aviscosity of 10 to 100,000 centipoise at 25° C.
 14. The composition ofclaim 1 wherein the MD_(b)D_(c)′D_(d)″M silicone M is trimethylsiloxy; Dis dimethylsiloxy; b is 1-50,000; D′ is RR⁴SiO_(1.0) wherein R is methyland R⁴ is a C₁₄₋₂₀ straight or branched chain alkyl; c is 1-50,000; andd is
 0. 15. The composition of claim 14 wherein R⁴ is C₁₆ and thesilicone is cetyl dimethicone.
 16. The composition of claim 1 whereinthe MD_(b)D_(c)′D_(d)″M silicone M is trimethylsiloxy; D isdimethylsiloxy; b is 1-50,000; D′ is RR⁴SiO_(1.0) wherein R is methyland R⁴ is a C₁₄₋₂₀ straight or branched chain alkyl; c is 1-50,000; D′is RR⁶SiO_(1.0) wherein R is methyl and R⁶ is (CH₂)_(o)—O—PE wherein ois 0-40 and PE is (—C₂H₄O)_(x)(—C₃H₆O)_(y)H and wherein x is 1-10,000and y is 0-10,000.
 17. The composition of claim 16 wherein the siliconeis cetyl dimethicone copolyol.
 18. The composition of claim 1 furthercomprising 1-50% by weight of the total composition of particulatematter.
 19. The composition of claim 1 further comprising 0.1-30% byweight of the total composition of one or more synthetic polymers. 20.The composition of claim 1 further comprising 0.1-70% by weight of thetotal composition of one or more waxes.